Gold(I)‐Catalyzed Nucleophilic Allylation of Azinium Ions with Allylboronates
نویسندگان
چکیده
Gold(I)-catalyzed nucleophilic allylations of pyridinium and quinolinium ions with various allyl pinacolboronates are reported. The reactions completely selective respect to the site azinium ion that is attacked, give functionalized 1,4-dihydropyridines 1,4-dihydroquinolines. Evidence suggests proceed through allylgold(I) intermediates formed by transmetalation from allylboronates. Density functional theory (DFT) calculations provided mechanistic insight.
منابع مشابه
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2022
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202202305